Running in heat 4, Dutee finished with a season-best timing of 23.85 but that hasn't led her to qualify for the semi-finals.
Christine Mboma topped the heat with a timing of 22.11 as she broke the Namibian national record.
Top three finishers from each of the seven heats and the next three fastest qualify for the semi-finals.
Dutee, who has a personal best of 23 seconds in 200 m event, ended at 38th overall out of 41 competitors.
Earlier, Dutee could not qualify for the 100m finals as she came in seventh in Heat 5 with a timing of 11:54 seconds.